Eric Knysz was arraigned Friday from the Mason County Jail. He also is charged with using a gun during a felony, car theft and being a habitual offender.
Trooper Paul Butterfield was shot in the head Monday in Sherman Township, about 80 miles north of Grand Rapids.
Knysz, of Lake County, was shot by another trooper during his arrest. He was appointed a public defender and ordered held without bond.
Sarah Knysz, 20, is charged with helping her husband try to escape. Both face Sept. 25 preliminary hearings.
Butterfield's funeral is today at Manistee High School.